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        Chloropropamide

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        Chloropropamide

        EINECS 202-314-5
        CAS No. 94-20-2 Density 1.334 g/cm3
        Solubility Insoluble in water Melting Point 128 °C
        Formula C10H13ClN2O3S Boiling Point
        Molecular Weight 276.76 Flash Point
        Transport Information Appearance white crystalline powder
        Safety 22-36 Risk Codes 20/21/22-40
        Molecular Structure Molecular Structure of 94-20-2 (1-(4-Chlorophenyl)sulfonyl-3-propylurea) Hazard Symbols HarmfulXn
        Synonyms

        Urea,1-[(p-chlorophenyl)sulfonyl]-3-propyl- (8CI);1-(p-Chlorobenzenesulfonyl)-3-propylurea;1-Propyl-3-(p-chlorobenzenesulfonyl)urea;Adiaben;Asucrol;Catanil;Chloronase;Diabaril;Diabechlor;Diabenal;Diabenese;Diabeneza;Diabet-Pages;Diabetoral;Diabinese;Glisema;Meldian;Melitase;Millinese;N-(p-Chlorobenzenesulfonyl)-N'-propylurea;NSC 44634;NSC 626720;P 607;Stabinol;U 9818;

         

        Chloropropamide Chemical Properties

        IUPAC Name: Chloropropamide
        The MF of Chlorpropamide (CAS NO.94-20-2) is C10H13ClN2O3S.

                                    
        The MW of Chlorpropamide (CAS NO.94-20-2) is 276.74.
        Synonyms of Chlorpropamide (CAS NO.94-20-2): 1-(4-chlorophenyl)sulfonyl-3-propyl-urea ; 4-Chlor-N-(propylcarbamoyl)benzolsulfonamid ; Benzenesulfonamide, 4-chloro-N-((propylamino)carbonyl)- ; Oradian
        Appearance: white crystalline powder
        Stability: Stable. Combustible
        Index of Refraction: 1.552 
        EINECS: 202-314-5
        Density: 1.334 g/ml 
        Melting Point: 128 °C
        Merck: 2186

        Chloropropamide Uses

          Chlorpropamide (CAS NO.94-20-2) is sulfonylurea oral hypoglycemic agents which mainly selectively act on the pancreatic islet-β-cells, promoting insulin secretion.Chlorpropamide has a relatively large side-effects, so the using of the drug are decreasing trend.

        Chloropropamide Production

         Chlorobenzene sulfonamide reacts with chlorobenzene sulfonyl amide,generating C urea sodium salt. Then hydrochloric acid, refined to derive. Another method is based on chlorobenzene sulfonamide, isopropyl isocyanate, triethylamine as raw materials.

        Chloropropamide Toxicity Data With Reference

        1.    

        sce-mus-orl 177 mg/kg

            MUREAV    Mutation Research. 77 (1980),349.
        2.    

        sce-ham-ipr 7100 µg/kg

            MUREAV    Mutation Research. 77 (1980),349.
        3.    

        orl-wmn TDLo:25 mg/kg/5D-I:BLD

            DICPBB    Drug Intelligence and Clinical Pharmacy. 18 (1984),981.
        4.    

        orl-wmn TDLo:300 mg/kg:CNS

            CTOXAO    Clinical Toxicology. 11 (1977),13.
        5.    

        orl-man TDLo:83 mg/kg/25D-I:GIT

            AJGAAR    American Journal of Gastroenterology. 80 (1985),381.
        6.    

        orl-rat LD50:2150 mg/kg

            FATOAO    Farmakologiya i Toksikologiya (Moscow). 25 (1962),93.
        7.    

        ipr-rat LD50:580 mg/kg

            TXAPA9    Toxicology and Applied Pharmacology. 18 (1971),185.
        8.    

        ivn-rat LD50:590 mg/kg

            PMDCAY    Progress in Medical Chemistry. 1 (1961),187.
        9.    

        orl-mus LD50:1546 mg/kg

            AIPTAK    Archives Internationales de Pharmacodynamie et de Therapie. 153 (1965),379.
        10.    

        ivn-mus LD50:500 mg/kg

            PMDCAY    Progress in Medical Chemistry. 1 (1961),187.

        Chloropropamide Consensus Reports

        NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-45 ,1978. . EPA Genetic Toxicology Program.

        Chloropropamide Safety Profile

        Moderately toxic by ingestion, intraperitoneal, and intravenous routes. Human systemic effects by ingestion: hemolysis with or without anemia, ulceration or bleeding from large intestine, cholestatic jaundice. Human teratogenic effects by ingestion: fetal death. Human reproductive effects by ingestion and possibly other routes: stillbirth, reduced viability and abnormal characteristics of newborn at birth. An experimental teratogen. Experimental reproductive effects. Mutation data reported. An antidiabetic agent. When heated to decomposition it emits very toxic fumes of Cl, NOx, and SOx.Safety information of Chlorpropamide (CAS NO.94-20-2):
        Hazard Codes  HarmfulXn
        Risk Statements 
        20/21/22 Harmful by inhalation, in contact with skin and if swallowed
        40 Limited evidence of a carcinogenic effect
        Safety Statements 
        22 Do not breathe dust
        36 Wear suitable protective clothing
        WGK Germany  3
        RTECS  YS6650000

        Chloropropamide Specification

        A halogenated amide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

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